Variability in the Structures of [4-(Aminomethyl)pyridine]silver(I) Complexes through Effects of Ligand Ratio, Anion, Hydrogen Bonding, and p://pubs.acs.org/images/gifchars/pi.gif" border

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• 作者：Rodney P. Feazell ; Cody E. Carson ; and Kevin K. Klausmeyer
• 刊名：Inorganic Chemistry
• 出版年：2006
• 出版时间：January 23, 2006
• 年：2006
• 卷：45
• 期：2
• 页码：935 - 944
• 全文大小：201K
• 年卷期：v.45,no.2(January 23, 2006)
• ISSN：1520-510X

文摘

The reaction of the asymmetric 4-(aminomethyl)pyridine (4-amp) ligand with silver(I) salts of trifluoromethanesulfonate(triflate, OTf^-), trifluoroacetate (tfa^-), or tetrafluoroborate (BF₄^-) have produced a variety of one- and two-dimensionalstructural motifs depending upon the ratio in which the components are mixed. When the proportion of ligand tometal is 1:1, linear coordination polymers are formed with silver(I) OTf^- (1) and tfa^- (2). Altering the ratio to 2:1,a linear polymer of corner-shared boxes (3) is formed with tfa^-, a linear box-in-box "chain link" polymer (4) isformed with OTf^-, and a two-dimensional sheet (5) is constructed with BF₄^-. Addition of 5,5'-dimethyl-2,2'-bipyridineto a solution of 4-ampAgBF₄ disrupts the polymerization of the previous structure and results in the constructionof the infinite metal-metal bound strings of 6a regardless of ratio of amp to silver present. H-bonding, pi.gif" BORDER=0 >-stacking,and closed-shell Ag-Ag interactions are all involved in the overall conformations of the final structures.