In Situ, Simultaneous Irradiation and Monitoring of a Photocatalyzed Organic Oxidation Reaction in a TiO2-Coated NMR Tube

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• 作者：Andrew Mills ; Christopher O鈥橰ourke
• 刊名：Journal of Organic Chemistry
• 出版年：2015
• 出版时间：October 16, 2015
• 年：2015
• 卷：80
• 期：20
• 页码：10342-10345
• 全文大小：269K
• ISSN：1520-6904

文摘

The semiconductor photocatalyzed (SPC) oxidation of toluene is performed inside an NMR spectrometer and the reaction is monitored simultaneously in situ, using a fiber optic probe/diffuser to provide the UV light to activate the titania photocatalyst coating on the inside of the NMR tube. Such a system has great potential for the simple rapid screening of a wide range of SPC mediated organic reactions.