文摘
The oxidation of aryl 1-methyl-1-phenylethyl sulfides promoted by the nonheme iron(IV)–oxo complexes [(N4Py)FeIV═O]2+ and [(Bn-TPEN)FeIV═O]2+ occurs by an electron transfer–oxygen rebound (ET–OT) mechanism leading to aryl 1-methyl-1-phenylethyl sulfoxides accompanied by products derived from Cα–S fragmentation of sulfide radical cations (2-phenyl-2-propanol and diaryl disulfides). For the first time, the rate constants for the oxygen rebound process (kOT), which are in the range of <0.8 × 104 to 3.5 × 104 s–1, were determined from the fragmentation rate constants of the radical cations (kf) and the S oxidation/fragmentation product ratios.