Chiral Dimeric Capsules from N,C-Linked Peptidocalix[4]arenes Self-Assembled through an Antiparallel -S

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• 作者：Francesco Sansone ; Laura Baldini ; Alessandro Casnati ; Elisa Chierici ; Giovanni Faimani ; Franco Ugozzoli ; and Rocco Ungaro
• 刊名：Journal of the American Chemical Society
• 出版年：2004
• 出版时间：May 26, 2004
• 年：2004
• 卷：126
• 期：20
• 页码：6204 - 6205
• 全文大小：99K
• 年卷期：v.126,no.20(May 26, 2004)
• ISSN：1520-5126

文摘

The first example of a calix[4]arene amino acid is reported. It allowed the synthesis of the novel N,C-linked peptidocalix[4]arenes which self-assemble in low-polarity media to give chiral dimeric capsules held together by an antiparallel -sheetlike hydrogen-bonding motif.