Unassisted 2-Coordination of Polycyclic Aromatic Hydrocarbons to Platinum(II)

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• 作者：Jesú ; s R. Berenguer ; Juan Fornié ; s ; L. Francisco Mart&iacute ; n ; Antonio Mart&iacute ; n ; and Babil Menjó ; n
• 刊名：Inorganic Chemistry
• 出版年：2005
• 出版时间：October 17, 2005
• 年：2005
• 卷：44
• 期：21
• 页码：7265 - 7267
• 全文大小：95K
• 年卷期：v.44,no.21(October 17, 2005)
• ISSN：1520-510X

文摘

The coordination of phenanthrene to the d⁸ Pt^II center in (SP-4-2)-[Pt(C₆F₅)₂(CO)(²-C₁₄H₁₀)] causes a slight pyramidalization atthe metal-bound C atoms (C⁹ and C¹⁰), but no perceptibleelongation of the corresponding C-C bond [C(13)-C(14) 132.0(5) vs. 133.8(5) pm in the free ligand].