Dissociative Chemisorption of Methane on Ni and Pt Surfaces: Mode-Specific Chemistry and the Effects of Lattice Motion
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- 作者：Sven Nave ; Ashwani K. Tiwari ; Bret Jackson
- 刊名：Journal of Physical Chemistry A
- 出版年：2014
- 出版时间：October 16, 2014
- 年：2014
- 卷：118
- 期：41
- 页码：9615-9631
- 全文大小：745K
- ISSN：1520-5215
文摘
The dissociative chemisorption of methane on metal surfaces is of great practical and fundamental interest. Not only is it the rate-limiting step in the steam re-forming of natural gas, but also the reaction exhibits interesting mode-specific behavior and a strong dependence on the temperature of the metal. Electronic structure methods are used to explore this reaction on various Ni and Pt surfaces, with a focus on how the transition state is modified by motion of the metal lattice atoms. These results are used to construct models that explain the strong variation in reactivity with substrate temperature, shown to result primarily from changes in the dissociation barrier height with lattice motion. The dynamics of the dissociative chemisorption of CH4 on Ni and Pt is explored, using a fully quantum approach based on the reaction path Hamiltonian that includes all 15 molecular degrees of freedom and the effects of lattice motion. Agreement with experiment is good, and vibrational excitation of the molecule is shown to significantly enhance reactivity. The efficacy for this is examined in terms of the vibrationally nonadiabatic couplings, mode softening, mode symmetry, and energy localization in the reactive bond.