Mechanically Induced Gelation of a Kinetically Trapped Supramolecular Polymer

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• 作者：Abraham J. P. Teunissen ; Marko M. L. Nieuwenhuizen ; Fransico Rodr铆guez-Llansola ; Anja R. A. Palmans ; E. W. Meijer
• 刊名：Macromolecules
• 出版年：2014
• 出版时间：December 9, 2014
• 年：2014
• 卷：47
• 期：23
• 页码：8429-8436
• 全文大小：431K
• ISSN：1520-5835

文摘

The stimuli-induced gelation of a urethane-functionalized ditopic ureidopyrimidinone (UPy) compound is presented, and the mechanism by which the gelation proceeds is proposed. In a 40鈥?20 mM solution in chloroform, the compound can exist in two different aggregated states, namely a low viscous mixture of (cyclic) oligomers or a fibrous gel. As evidenced by IR, NMR, and WAXS, the liquid state is stabilized by hydrogen bonds between the UPy and the back-folded chain, while the fibrous gel is stabilized by lateral hydrogen bonds within stacked UPy dimers. Controlled preparation techniques allow for pathway selection to arrive at one of both states. The remarkable long-term stability of the low viscous state (over 2 months for a 80 mM solution) is in contrast to the fast transformation into a gel by stirring in a few hours. Other mechanical stimuli like shaking, sonicating, and stirring for a shorter period, as well as freezing and thawing the solution, yield weaker gels than those obtained by long stirring. Heating the gels and slow cooling reversibly yield the nonviscous solution. This shows that the formation of UPy鈥搖rethane hydrogen bonds kinetically traps the UPy polymers, thereby preventing their lateral aggregation. The application of mechanical stress or freezing disrupts this interaction, allowing for the formation of a stacked nucleus on which further material can grow, eventually leading to gelation of the solution.