Dehydrogenative Oxidation of Alcohols in Aqueous Media Using Water-Soluble and Reusable Cp*Ir Catalysts Bearing a Functional Bipyridine Ligand

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• 作者：Ryoko Kawahara ; Ken-ichi Fujita ; Ryohei Yamaguchi
• 刊名：The Journal of the American Chemical Society
• 出版年：2012
• 出版时间：February 29, 2012
• 年：2012
• 卷：134
• 期：8
• 页码：3643-3646
• 全文大小：297K
• 年卷期：v.134,no.8(February 29, 2012)
• ISSN：1520-5126

文摘

A new catalytic system for the dehydrogenative oxidation of alcohols using a water-soluble Cp*Ir complex bearing a bipyridine-based functional ligand as catalyst has been developed. With this catalytic system, a variety of primary and secondary alcohols have been efficiently converted to aldehydes and ketones, respectively, in aqueous media without using any oxidant. Reuse of the catalyst by a very simple procedure has been also accomplished.