Luminescent Hyperbranched Polymers: Combining Thiol-Yne Chemistry with Gold-Mediated C鈭扝 Bond Activation

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• 作者：Dominik Konkolewicz ; Sylvain Gaillard ; Andrew G. West ; Yuen Yap Cheng ; Angus Gray-Weale ; Timothy W. Schmidt ; Steven P. Nolan ; Se虂bastien Perrier
• 刊名：Organometallics
• 出版年：2011
• 出版时间：March 28, 2011
• 年：2011
• 卷：30
• 期：6
• 页码：1315-1318
• 全文大小：764K
• 年卷期：v.30,no.6(March 28, 2011)
• ISSN：1520-6041

文摘

A highly efficient and straightforward synthetic method, leading to the formation of a luminescent hyperbranched polymer, is described. The simple polymer functionalization step takes advantage of the reactivity of relatively acidic alkyne C鈭扝 bonds with a basic [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) synthon.