文摘
Metallic silver (ranging from 1 to 10 wt %) was deposited onto a graphite-like carbon nitride photocatalyst through a microemultion method. Surface, morphological, and structural properties of the resulting materials were characterized using BET and porosity measurements, X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, and UV–vis and photoluminescence spectroscopy. The activity of the composite samples under sunlight-type and visible illumination was measured for toluene photodegradation and was analyzed by means of the reaction rate and the quantum efficiency parameter. To obtain the latter observable, the lamp emission properties as well as the radiation field interaction with the catalyst inside the reactor were modeled and numerically calculated. The stability of the samples under both illumination conditions was also studied. The results evidence that the composite samples containing 1–10 silver wt % outperform carbon nitride for sunlight-type and visible illumination, but the optimal use of the charge generated after light absorption is obtained for the sample with 1 wt % of silver acording to the quantum efficiency calculation. The study shows that the optimum silver–g-Cb>3b>Nb>4b> contact is able to outperform TiOb>2b> reference systems (nano-TiOb>2b> and P25) under sunlight illumination and points out that this occurs as a direct consequence of the charge handling through the interface between catalyst components. This indicates that composite systems based on g-Cb>3b>Nb>4b> can be competitive in sunlight-triggered photodegradation processes to eliminate tough polluctants such as toluene, rendering active and stable systems.