Synthesis of Biodegradable Macroporous Poly(l-lactide)/Poly(ε-caprolactone) Blend Using Oil-in-Eutectic-Mixture High-Internal-Phase Emulsions as Template

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• 作者：María G. Pérez-García ; María C. Gutiérrez ; Josué D. Mota-Morales ; Gabriel Luna-Bárcenas ; Francisco del Monte
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2016
• 出版时间：July 6, 2016
• 年：2016
• 卷：8
• 期：26
• 页码：16939-16949
• 全文大小：595K
• 年卷期：0
• ISSN：1944-8252

文摘

We have demonstrated that l-lactide (LLA) forms a eutectic mixture with ε-caprolactone (CL) in a 30:70 mol ratio with a melting point of −19 °C. Taking advantage of the liquid nature and polarity at the LLA–CL eutectic mixture, we have formulated oil-in-eutectic-mixture high-internal-phase emulsions (HIPEs) by stepwise addition of the oil phase (tetradecane) into the continuous phase (mixture of surfactant and LLA−CL eutectic mixture) at room temperature and under stirring. The oil-in-LLA–CL-eutectic-mixture HIPEs were polymerized in the presence of both the organocatalysts 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) and methanesulfonic acid (MSA) and the initiator benzyl alcohol (BnOH) at 37 °C and without the addition of any extra reagent or solvent in one single pot. The catalytic selectivities of DBU and MSA for the ring-opening polymerizations of LLA and CL, respectively, allowed the synthesis of macroporous poly(l-lactide)/poly(ε-caprolactone) blend materials. The resulting materials exhibited a macroporous morphology that resembled that of the HIPE internal-phase droplets used as templates. These materials proved effective as oil absorbents for oil/water separation with not only a noticeable performance, similar to that of conventional sorbents in terms of both selectivity and recyclability, but also unprecedented safe disposability, certainly of interest for applications in the cleanup of industrial oily wastewaters and oil spills, thanks to the biodegradable features of both poly(ε-caprolactone) and poly(l-lactide).