Spin Transition Charted in a Fluorophore-Tagged Thermochromic Dinuclear Iron(II) Complex

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• 作者：Yann Garcia ; Fran莽ois Robert ; Anil D. Naik ; Guangyuan Zhou ; Bernard Tinant ; Koen Robeyns ; S茅bastien Michotte ; Luc Piraux
• 刊名：Journal of the American Chemical Society
• 出版年：2011
• 出版时间：October 12, 2011
• 年：2011
• 卷：133
• 期：40
• 页码：15850-15853
• 全文大小：782K
• 年卷期：v.133,no.40(October 12, 2011)
• ISSN：1520-5126

文摘

The first crystal structures of a dinuclear iron(II) complex with three N1,N2-1,2,4-triazole bridges in the high-spin and low-spin states are reported. Its sharp spin transition, which was probed using X-ray, calorimetric, magnetic, and ⁵⁷Fe Mossbauer analyses, is also delineated in the crystalline state by variable-temperature fluorimetry for the first time.