Spontaneous Nucleation and Growth of GaN Nanowires: The Fundamental Role of Crystal Polarity
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- 作者：Sergio Fern谩ndez-Garrido ; Xiang Kong ; Tobias Gotschke ; Raffaella Calarco ; Lutz Geelhaar ; Achim Trampert ; Oliver Brandt
- 刊名：Nano Letters
- 出版年：2012
- 出版时间：December 12, 2012
- 年：2012
- 卷：12
- 期：12
- 页码：6119-6125
- 全文大小：521K
- 年卷期：v.12,no.12(December 12, 2012)
- ISSN：1530-6992
文摘
We experimentally investigate whether crystal polarity affects the growth of GaN nanowires in plasma-assisted molecular beam epitaxy and whether their formation has to be induced by defects. For this purpose, we prepare smooth and coherently strained AlN layers on 6H-SiC(0001) and SiC(0001虆) substrates to ensure a well-defined polarity and an absence of structural and morphological defects. On N-polar AlN, a homogeneous and dense N-polar GaN nanowire array forms, evidencing that GaN nanowires form spontaneously in the absence of defects. On Al-polar AlN, we do not observe the formation of Ga-polar GaN NWs. Instead, sparse N-polar GaN nanowires grow embedded in a Ga-polar GaN layer. These N-polar GaN nanowires are shown to be accidental in that the necessary polarity inversion is induced by the formation of SixN. The present findings thus demonstrate that spontaneously formed GaN nanowires are irrevocably N-polar. Due to the strong impact of the polarity on the properties of GaN-based devices, these results are not only essential to understand the spontaneous formation of GaN nanowires but also of high technological relevance.