Cu(I)(2,9-Bis(trifluoromethyl)-1,10-phenanthroline)2+ Complexes: Correlation between Solid-State Structure and Photoluminescent Properties
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- 作者：Andrey Yu. Kovalevsky ; Milan Gembicky ; and Philip Coppens
- 刊名：Inorganic Chemistry
- 出版年：2004
- 出版时间：December 27, 2004
- 年：2004
- 卷：43
- 期：26
- 页码：8282 - 8289
- 全文大小：263K
- 年卷期：v.43,no.26(December 27, 2004)
- ISSN：1520-510X
文摘
The 90K solid-state structures, room temperature absorption, and room temperature and 17 K emission spectra ofseven different salts of [Cu(I)(bfp)2]+ (bfp = 2,9-bis(trifluoromethyl)-1,10-phenanthroline) have been determined. Toquantify the distortion of the Cu coordination environment, a distortion parameter 
is defined that is a combinedmeasure of the flattening, rocking, and wagging distortions of the complex cations. In general, the distortion in the(bfp) cations is less than found previously for Cu(I)(dmp)2 (dmp = 2,9-dimethyl-1,10-phenanthroline) salts, in particularthe flattening is reduced because of the bulkier 2,9-substituents. The 17 K lifetimes range up to 1.8 
s in theseries of solids examined and, with the marked exception of the BF4- salt, correlate linearly with the distortionparameter . The emission wavelength red-shifts with decreasing lifetime, which implies that an increased ground-state distortion is associated with a smaller energy gap.
is defined that is a combinedmeasure of the flattening, rocking, and wagging distortions of the complex cations. In general, the distortion in the(bfp) cations is less than found previously for Cu(I)(dmp)2 (dmp = 2,9-dimethyl-1,10-phenanthroline) salts, in particularthe flattening is reduced because of the bulkier 2,9-substituents. The 17 K lifetimes range up to 1.8 s in theseries of solids examined and, with the marked exception of the BF4- salt, correlate linearly with the distortionparameter . The emission wavelength red-shifts with decreasing lifetime, which implies that an increased ground-state distortion is associated with a smaller energy gap.