Non-Band-Gap Photoexcitation of Hydroxylated TiO2

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• 作者：Yu Zhang ; Daniel T. Payne ; Chi L. Pang ; Helen H. Fielding ; Geoff Thornton
• 刊名：The Journal of Physical Chemistry Letters
• 出版年：2015
• 出版时间：September 3, 2015
• 年：2015
• 卷：6
• 期：17
• 页码：3391-3395
• 全文大小：354K
• ISSN：1948-7185

文摘

The photochemistry of TiO₂ has been studied intensively since it was discovered that TiO₂ can act as a photocatalyst. Nevertheless, it has proven difficult to establish the detailed charge-transfer processes involved, partly because the excited states involved are difficult to study. Here we present evidence of the existence of hydroxyl-induced excited states in the conduction band region. Using two-photon photoemission, we show that stepwise photoexcitation from filled band gap states lying 0.8 eV below the Fermi level of rutile TiO₂(110) excites hydroxyl-induced states 2.73 eV above the Fermi level that has an onset energy of 鈭?.1 eV. The onset is shifted to lower energy by the coadsorption of molecular water, which suggests a means of tuning the energy of the excited state.