Layered-to-Rock-Salt Transformation in Desodiated NaxCrO2 (x 0.4)

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• 作者：Shou-Hang Bo ; Xin Li ; Alexandra J. Toumar ; Gerbrand Ceder
• 刊名：Chemistry of Materials
• 出版年：2016
• 出版时间：March 8, 2016
• 年：2016
• 卷：28
• 期：5
• 页码：1419-1429
• 全文大小：645K
• ISSN：1520-5002

文摘

O3 layered sodium transition metal oxides (i.e., NaMO₂, M = Ti, V, Cr, Mn, Fe, Co, Ni) are a promising class of cathode materials for Na-ion battery applications. These materials, however, all suffer from severe capacity decay when the extraction of Na exceeds certain capacity limits. Understanding the causes of this capacity decay is critical to unlocking the potential of these materials for battery applications. In this work, we investigate the structural origins of capacity decay for one of the compounds in this class, NaCrO₂. The (de)sodiation processes of NaCrO₂ were studied both in situ and ex situ through X-ray and electron diffraction measurements. We demonstrate that Na_xCrO₂ (0 < x < 1) remains in the layered structural framework without Cr migration up to a composition of Na_0.4CrO₂. Further removal of Na beyond this composition triggers a layered-to-rock-salt transformation, which converts P′3-Na_0.4CrO₂ into the rock-salt CrO₂ phase. This structural transformation proceeds via the formation of an intermediate O3 Na_δCrO₂ phase that contains Cr in both Na and Cr slabs and shares very similar lattice dimensions with those of rock-salt CrO₂. It is intriguing to note that intercalation of alkaline ions (i.e., Na⁺ and Li⁺) into the rock-salt CrO₂ and O3 Na_δCrO₂ structures is actually possible, albeit in a limited amount (∼0.2 per formula unit). When these results were analyzed under the context of electrochemistry data, it was apparent that preventing the layered-to-rock-salt transformation is crucial to improve the cyclability of NaCrO₂. Possible strategies for mitigating this detrimental phase transition are proposed.