Symmetrically Substituted nido-Carboranylphthalocyanines: Facile Synthesis, Characterization, and Solution Properties. Evidence for Intra- and Intermolecular H+/K+ Exchang

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• 作者：Daniela Pietrangeli ; Angela Rosa ; Antonietta Pepe ; Giampaolo Ricciardi
• 刊名：Inorganic Chemistry
• 出版年：2011
• 出版时间：June 6, 2011
• 年：2011
• 卷：50
• 期：11
• 页码：4680-4682
• 全文大小：715K
• 年卷期：v.50,no.11(June 6, 2011)
• ISSN：1520-510X

文摘

The direct, non ex post synthesis of a novel phthalocyanine decorated with eight thiohexyl-nido-carborane functions, nido-[H₂MCHESPc]K₈, where the anionic polyhedra are in the form of K⁺ salt, is reported and discussed. The solution properties of this compound, including the unprecedented exchange between the pyrrolic protons and the peripheral alkali-metal ions, are also analyzed.