2-Pyrrolyloximes in High-Nuclearity Transition-Metal Cluster Chemistry: Fe10 and Fe12

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• 作者：Evangelia S. Koumousi ; Anastasia Routzomani ; Tu N. Nguyen ; Dimosthenis P. Giannopoulos ; Catherine P. Raptopoulou ; Vassilis Psycharis ; George Christou ; Theocharis C. Stamatatos
• 刊名：Inorganic Chemistry
• 出版年：2013
• 出版时间：February 4, 2013
• 年：2013
• 卷：52
• 期：3
• 页码：1176-1178
• 全文大小：223K
• 年卷期：v.52,no.3(February 4, 2013)
• ISSN：1520-510X

文摘

The employment of 2-pyrrolyloximes in high-nuclearity transition-metal cluster chemistry has provided access to unprecedented decanuclear and dodecanuclear Fe^III cagelike clusters bearing the anion of pyrrole-2-carboxaldehyde oxime (praoH₂), the simplest member of this new family of ligands; the identity of the products depends on the nature of the counteranion present in the starting materials.