Chemoselective Samarium-Mediated Benzoyloxysulfone Eliminations

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• 作者：Erasmus O. Volz ; Gregory W. O鈥橬eil
• 刊名：Journal of Organic Chemistry
• 出版年：2011
• 出版时间：October 21, 2011
• 年：2011
• 卷：76
• 期：20
• 页码：8428-8432
• 全文大小：782K
• 年卷期：v.76,no.20(October 21, 2011)
• ISSN：1520-6904

文摘

An investigation of the substrate dependence on the rate of samarium-mediated reductive elimination of 尾-acyloxysulfones has provided insights into the mechanism of this transformation and allowed for the development of a chemoselective elimination process.