Dissolution of Brominated Epoxy Resins by Dimethyl Sulfoxide To Separate Waste Printed Circuit Boards

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• 作者：Ping Zhu ; Yan Chen ; Liangyou Wang ; Guangren Qian ; Wei Jie Zhang ; Ming Zhou ; Jin Zhou
• 刊名：Environmental Science & Technology (ES&T)
• 出版年：2013
• 出版时间：March 19, 2013
• 年：2013
• 卷：47
• 期：6
• 页码：2654-2660
• 全文大小：406K
• 年卷期：v.47,no.6(March 19, 2013)
• ISSN：1520-5851

文摘

Improved methods are required for the recycling of waste printed circuit boards (WPCBs). In this study, WPCBs (1鈥?.5 cm²) were separated into their components using dimethyl sulfoxide (DMSO) at 60 掳C for 45 min and a metallographic microscope was used to verify their delamination. An increased incubation time of 210 min yielded a complete separation of WPCBs into their components, and copper foils and glass fibers were obtained. The separation time decreased with increasing temperature. When the WPCB size was increased to 2鈥? cm², the temperature required for complete separation increased to 90 掳C. When the temperature was increased to 135 掳C, liquid photo solder resists could be removed from the copper foil surfaces. The DMSO was regenerated by rotary decompression evaporation, and residues were obtained. Fourier transform infrared spectroscopy (FT-IR), thermal analysis, nuclear magnetic resonance, scanning electron microscopy, and energy-dispersive X-ray spectroscopy were used to verify that these residues were brominated epoxy resins. From FT-IR analysis after the dissolution of brominated epoxy resins in DMSO it was deduced that hydrogen bonding may play an important role in the dissolution mechanism. This novel technology offers a method for separating valuable materials and preventing environmental pollution from WPCBs.