Pd(0)-Catalyzed Diarylation of sp3 C鈭扝 Bond in (2-Azaaryl)methanes
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- 作者：Guoyong Song ; Yan Su ; Xue Gong ; Keli Han ; Xingwei Li
- 刊名：Organic Letters
- 出版年：2011
- 出版时间：April 15, 2011
- 年：2011
- 卷：13
- 期：8
- 页码：1968-1971
- 全文大小：782K
- 年卷期：v.13,no.8(April 15, 2011)
- ISSN：1523-7052
文摘
A highly efficient and selective palladium-catalyzed diarylation of (2-azaaryl)methanes at the methyl group is described. Aryl chlorides proved reactive enough. A palladium 畏3-azaallyl intermediate has been identified on the basis of DFT studies.