Water-Responsive Internally Structured Polymer鈥揝urfactant Films on Solid Surfaces

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• 作者：Charlotte Gustavsson ; Joaquim Li ; Karen J. Edler ; Lennart Piculell
• 刊名：Langmuir
• 出版年：2014
• 出版时间：October 28, 2014
• 年：2014
• 卷：30
• 期：42
• 页码：12525-12531
• 全文大小：584K
• ISSN：1520-5827

文摘

Water-insoluble films of oppositely charged polyion鈥搒urfactant ion 鈥渃omplex salts鈥?(CS) are readily cast on solid surfaces from ethanolic solutions. The methodology introduces new possibilities to study and utilize more or less hydrated CS. Direct SAXS measurements show that the surface films are water-responsive and change their liquid crystalline structure in response to changes in the water activity of the environment. In addition to the classical micellar cubic and hexagonal phases, a rectangular ribbon phase and a hexagonal close-packed structure have now been detected for CS composed of cationic alkyltrimethylammonium surfactants with polyacrylate counterions. Added cosurfactants, decanol or the nonionic surfactant C₁₂E₅, yield additional lamellar and bicontinuous cubic structures. Images of the surfaces by optical and atomic force microscopy show that the films cover the surfaces well but have a more or less irregular surface topology, including 鈥渃raters鈥?of sizes ranging from a few to hundreds of micrometers. The results indicate possibilities to create a wealth of water-responsive structured CS films on solid surfaces.