Stereoselective Syntheses of Rolliniastatin 1, Rollimembrin, and Membranacin
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- 作者：Gyochang Keum ; Cheol Hee Hwang ; Soon Bang Kang ; Youseung Kim ; and Eun Lee
- 刊名：Journal of the American Chemical Society
- 出版年：2005
- 出版时间：July 27, 2005
- 年：2005
- 卷：127
- 期：29
- 页码：10396 - 10399
- 全文大小：173K
- 年卷期：v.127,no.29(July 27, 2005)
- ISSN：1520-5126
文摘
A radical cyclization of 
-alkoxyvinyl sulfoxides-Pummerer rearrangement-allylation protocolwas successfully applied to the synthesis of the threo/cis/threo/cis/erythro bis-oxolane moiety in rolliniastatin1 (1), rollimembrin (2), and membranacin (3).
-alkoxyvinyl sulfoxides-Pummerer rearrangement-allylation protocolwas successfully applied to the synthesis of the threo/cis/threo/cis/erythro bis-oxolane moiety in rolliniastatin1 (1), rollimembrin (2), and membranacin (3).