Suprachannel as a Radical Trap: Crystal Structure of Single Carbon Radicals

详细信息    查看全文

• 作者：Yoonjung Cho ; Tae Hwan Noh ; Jeong Gyun Kim ; Haeri Lee ; Ok-Sang Jung
• 刊名：Crystal Growth & Design
• 出版年：2016
• 出版时间：June 1, 2016
• 年：2016
• 卷：16
• 期：6
• 页码：3054-3058
• 全文大小：341K
• 年卷期：0
• ISSN：1528-7505

文摘

We report proof-of-concept experiments on the unprecedented crystal structure of an iodomethyl radical (·CH₂I) nestled within an ensemble’s suprachannel via single crystal-to-single crystal photoreaction without destruction of the suprachannel. The trapped nonconjugated carbon radical was additionally confirmed by EPR, ¹³C MAS, UPS, and Raman spectra.