Taming of the Silver FOX

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• 作者：Sonali Garg ; Haixiang Gao ; Young-Hyuk Joo ; Damon A. Parrish ; Yangen Huang ; Jean’ ; ne M. Shreeve
• 刊名：Journal of the American Chemical Society
• 出版年：2010
• 出版时间：July 7, 2010
• 年：2010
• 卷：132
• 期：26
• 页码：8888-8890
• 全文大小：165K
• 年卷期：v.132,no.26(July 7, 2010)
• ISSN：1520-5126

文摘

The first silver-FOX, silver-ammonia-FOX, and silver-amine-FOX compounds were synthesized by the reactions of silver nitrate with K-FOX or guanidine-FOX in water, aqueous ammonia, and amines, respectively. The crystal structure of silver-ammonia-FOX exhibits unique covalent bonding behavior, which is supported by NBO calculations.