Experimental and Modeling Studies on the Solubility of d-Arabinose, d-Fructose, d-Glucose,
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- 作者：Robert-Jan van Putten ; Jozef G. M. Winkelman ; Farhad Keihan ; Jan C. van der Waal ; Ed de Jong ; Hero J. Heeres
- 刊名：Industrial & Engineering Chemistry Research
- 出版年：2014
- 出版时间：May 14, 2014
- 年：2014
- 卷：53
- 期：19
- 页码：8285-8290
- 全文大小：357K
- 年卷期：v.53,no.19(May 14, 2014)
- ISSN：1520-5045
文摘
The solubilities of d-glucose, d-arabinose, d-xylose, d-fructose, d-mannose, and sucrose in methanol and methanol鈥搘ater mixtures (<25 wt % water) were determined at temperatures between 295 and 353 K using a unique high-throughput screening technique. The data were modeled with a UNIQUAC framework with an average error between calculated and experimental data of 3.7%. The results provide input for the design of efficient chemical processes for the conversion of these sugars into valuable biobased building blocks in methanol鈥搘ater mixtures.