Electronic Structure of Water Molecules Confined in a Micelle Lattice

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• 作者：Johan Grå ; sj ; Egil Andersson ; Johan Forsberg ; Emad F. Aziz ; Barbara Brena ; Christian Johansson ; Joseph Nordgren ; Laurent Duda ; Joakim Andersson ; Franz Hennies ; Jan-Erik Rubensson ; Per Hansson
• 刊名：Journal of Physical Chemistry B
• 出版年：2009
• 出版时间：June 18, 2009
• 年：2009
• 卷：113
• 期：24
• 页码：8201-8205
• 全文大小：198K
• 年卷期：v.113,no.24(June 18, 2009)
• ISSN：1520-5207

文摘

Oxygen K absorption and emission spectra of water molecules confined in dodecyltrimethyl ammonium chloride micelle structures are presented. The local electronic structure of the water molecules is found to be dramatically different from the electronic structure of water molecules in the gas-phase as well as in liquid water. Hybridization with states of the ions in the surrounding ions is directly observed, and evidence for stabilization of the water molecules relative to molecules in bulk water is found.