Unimolecular Electrical Rectification in Hexadecylquinolinium Tricyanoquinodimethanide
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- 作者：Robert M. Metzger ; Bo Chen ; Ulf Hö ; pfner ; M. V. Lakshmikantham ; Dominique Vuillaume ; Tsuyoshi Kawai ; Xiangli Wu ; Hiroaki Tachibana ; Terry V. Hughes ; Hiromi Sakurai ; Jeffrey W. Baldwin ; Christina H
- 刊名：Journal of the American Chemical Society
- 出版年：1997
- 出版时间：October 29, 1997
- 年：1997
- 卷：119
- 期：43
- 页码：10455 - 10466
- 全文大小：368K
- 年卷期：v.119,no.43(October 29, 1997)
- ISSN：1520-5126
文摘
Macroscopic and nanoscopic current-voltage measurements revealasymmetries in the DC electricalconductivity through Langmuir-Blodgett multilayers and evenmonolayers of 
-(n-hexadecyl)quinolinumtricyanoquinodimethanide, C16H33Q-3CNQ (5).These asymmetries are due to a transition of the ground-statezwitterion toan excited-state conformer which is probably neutral. Unimolecularelectrical rectification by monolayers of 5 isunequivocally confirmed.
-(n-hexadecyl)quinolinumtricyanoquinodimethanide, C16H33Q-3CNQ (5).These asymmetries are due to a transition of the ground-statezwitterion toan excited-state conformer which is probably neutral. Unimolecularelectrical rectification by monolayers of 5 isunequivocally confirmed.