Novel Bis(ethylenedithio)tetrathiafulvalene-Based Organic Conductor with 1,1'-Ferrocenedisulfonate

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• 作者：Hiroki Akutsu ; Ryo Ohnishi ; Jun-ich Yamada ; Shin'ichi Nakatsuji ; Scott S. Turner
• 刊名：Inorganic Chemistry
• 出版年：2007
• 出版时间：October 15, 2007
• 年：2007
• 卷：46
• 期：21
• 页码：8472 - 8474
• 全文大小：138K
• 年卷期：v.46,no.21(October 15, 2007)
• ISSN：1520-510X

文摘

A new bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF)-based saltwith a ferrocenyl moiety, ' ''-(BEDT-TTF)₄(Fe(C₅H₄SO₃)₂)·6H₂O,has been prepared. The ferrocenyl part of this salt is neutral anddiamagnetic, but the magnetic susceptibility is well modeled by aCurie-Weiss law with C = 0.142 emu·K·mol^-1 (¹/₃ of s = ¹/₂spin). The spin is likely to be localized on the donor layer becauseof its unique charge disproportionation.