Spirodiepoxide-Based Cascades: Direct Access to Diverse Motifs
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- 作者：Rojita Sharma ; Madhuri Manpadi ; Yue Zhang ; Hiyun Kim ; Novruz G. Ahkmedov ; Lawrence J. Williams
- 刊名：Organic Letters
- 出版年：2011
- 出版时间：July 1, 2011
- 年：2011
- 卷：13
- 期：13
- 页码：3352-3355
- 全文大小：770K
- 年卷期：v.13,no.13(July 1, 2011)
- ISSN：1523-7052
文摘
Allene epoxide formation/opening reaction sequences enabled direct access to diverse products. Described here are a single flask procedure for allene preparation and allene oxidation/derivatization reactions that give, among others, diendiol, diyndiol, 伪鈥?hydroxy-纬-enone, dihydrofuranone, butenolide, and 未-lactone products.