Multicolored, Low-Power, Flexible Electrochromic Devices Based on Ion Gels

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• 作者：Hong Chul Moon ; Chang-Hyun Kim ; Timothy P. Lodge ; C. Daniel Frisbie
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2016
• 出版时间：March 9, 2016
• 年：2016
• 卷：8
• 期：9
• 页码：6252-6260
• 全文大小：680K
• ISSN：1944-8252

文摘

Ion gels composed of a copolymer and a room temperature ionic liquid are versatile solid-state electrolytes with excellent features including high ionic conductivity, nonvolatility, easily tunable mechanical properties, good flexibility and solution processability. Ion gels can be functionalized by incorporating redox-active species such as electrochemiluminescent (ECL) luminophores or electrochromic (EC) dyes. Here, we enhance the functionality of EC gels for realizing multicolored EC devices (ECDs), either by controlling the chemical equilibrium between a monomer and dimer of a colored EC species, or by modifying the molecular structures of the EC species. All devices in this work are conveniently fabricated by a “cut-and-stick” strategy, and require very low power for maintaining the colored state [i.e., 90 μW/cm² (113 μA/cm² at −0.8 V) for blue, 4 μW/cm² (10 μA/cm² at −0.4 V) for green, and 32 μW/cm² (79 μA/cm² at −0.4 V) for red ECD]. We also successfully demonstrate a patterned, multicolored, flexible ECD on plastic. Overall, these results suggest that gel-based ECDs have significant potential as low power displays in printed electronics powered by thin-film batteries.