Catalysis Kinetics and Porous Analysis of Rolling Activated Carbon-PTFE Air-Cathode in Microbial Fuel Cells

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• 作者：Heng Dong ; Hongbing Yu ; Xin Wang
• 刊名：Environmental Science & Technology (ES&T)
• 出版年：2012
• 出版时间：December 4, 2012
• 年：2012
• 卷：46
• 期：23
• 页码：13009-13015
• 全文大小：383K
• 年卷期：v.46,no.23(December 4, 2012)
• ISSN：1520-5851

文摘

The microbial fuel cell (MFC), being an environment-friendly technology for wastewater treatment, is limited by low efficiency and high cost. Power output based on capital cost had been greatly increased in our previous work by introducing a novel activated carbon (AC) air-cathode (ACAC). The catalysis behavior of this ACAC was studied here based on catalysis kinetics and pore analysis of both carbon powders and catalyst layers (CLs). Plain AC (AC1#), ultracapacitor AC (AC2#), and non-AC (XC-72) powders were used as catalysts. The electron transfer number (n) of oxygen reduction reaction (ORR) with CLs increased by 5鈥?3% compared to those n values of corresponding carbon powders before being rolled to CLs with PTFE, while the n value of Pt/C decreased by 38% when it was brushed with Nafion as the CL, indicating that rolling procedure with PTFE binder substantially increased the catalytic activity of carbon catalysts. Two鈥揻our times larger in micropore area of AC powders than non-AC powder resulted in 1.3鈥?.9 times increase in power density of MFCs. In addition, more uniform distribution of microporosity was found in AC1# than in AC2#, which could be the reason for the 25% increase in power density of ACAC1# (1355 卤 26 mW路m^鈥?) compared to 1086 卤 8 mW路m^鈥? of ACAC2#.