Measurement of Solid鈥揕iquid Phase Equilibrium for the Ternary 3-Nitrophthalic Anhydride + 4-Nitrophthalic Anhydride + 1,4-Dioxane System

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• 作者：Fangli Qiu ; Jianguo Yang ; Guobo Huang ; Huanan Hu ; Siying Yu ; Hongkun Zhao ; Rongrong Li
• 刊名：Journal of Chemical & Engineering Data
• 出版年：2014
• 出版时间：May 8, 2014
• 年：2014
• 卷：59
• 期：5
• 页码：1583-1587
• 全文大小：258K
• 年卷期：v.59,no.5(May 8, 2014)
• ISSN：1520-5134

文摘

In this work, solid鈥搇iquid equilibria (SLE) data for the ternary 3-nitrophthalic anhydride + 4-nitrophthalic anhydride + 1,4-dioxane system were obtained at (283.15, 303.15, and 323.15) K. The solid鈥搇iquid phase diagrams of the ternary system were constructed based on the measured solubility data. There existed two pure solid phases at each temperature in the studied system, pure 3-nitrophthalic anhydride and 4-nitrophthalic anhydride, which were identified by the wet residue method of Schreinemaker. Furthermore, the density (蟻) of the equilibrium liquid phase was determined. The ternary phase diagram and solubility data for the system 3-nitrophthalic anhydride + 4-nitrophthalic anhydride + 1,4-dioxane, which shows a much more practical application for the region where pure 3-nitrophthalic anhydride and 4-nitrophthalic anhydride are obtained, are much larger than those in the system with 2-propanone as a solvent.