Polymer/Ionic Liquid Thermoplastic Electrolytes for Energy Storage Processed by Solvent Free Procedures

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• 作者：A. Mejía ; E. Benito ; J. Guzmán ; L. Garrido ; N. García ; M. Hoyos ; P. Tiemblo
• 刊名：ACS Sustainable Chemistry & Engineering
• 出版年：2016
• 出版时间：April 4, 2016
• 年：2016
• 卷：4
• 期：4
• 页码：2114-2121
• 全文大小：437K
• ISSN：2168-0485

文摘

A series of poly(ethylene oxide) (PEO)/lithium trifluoromethanesulfonate (LiTf)/room temperature ionic liquid (RTIL) composite electrolytes has been prepared by melt compounding, using sepiolite modified with mallcaps">d-α-tocopherol polyethylene glycol 1000 succinate (TPGS-Sep) as filler. These electrolytes have been extensively characterized, including thermal stability, relaxations and transitions, rheology, conductivity, ion diffusivity, and salt dissociation. This work shows how the ability of TPGS-S to act as a physical cross-linking site for PEO allows these electrolytes to behave as solids at T > 70 °C, while the abundance of an ionic liquid phase makes the ion diffusion coefficients at 25 °C considerably high, closer to those of a viscous liquid than to those of a solid phase. This combination of rheological and electrical properties, together with their simple and scalable preparation by melt-compounding, makes them a very appealing new class of sustainable electrolytes. This same concept can be applied to electrolytes with other types of salts, and therefore, electrolytes incorporating Al³⁺, Mg²⁺, or Na⁺ salts can be similarly prepared.