A Tetranuclear, Macrocyclic 3d鈭?f Complex Showing Single-Molecule Magnet Behavior

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• 作者：Humphrey L. C. Feltham ; Rodolphe Cl茅rac ; Annie K. Powell ; Sally Brooker
• 刊名：Inorganic Chemistry
• 出版年：2011
• 出版时间：May 16, 2011
• 年：2011
• 卷：50
• 期：10
• 页码：4232-4234
• 全文大小：719K
• 年卷期：v.50,no.10(May 16, 2011)
• ISSN：1520-510X

文摘

[Cu^II₃Tb^III(L^Pr)(NO₃)₂(MeOH)(H₂O)₂](NO₃)路3H₂O is a rare example of a 3d鈭?f single-molecule magnet prepared using a macrocyclic ligand: at low T, it exhibits frequency-dependent alternating-current susceptibility, indicative of slow relaxation of the magnetization.