Metastable One-Dimensional AgCl1-xIx Solid-Solution Wurzite "Tunnel" Crystals Formed within Single-Walled Carbon Nanotub
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- 作者：Jeremy Sloan ; Mauricio Terrones ; Stefan Nufer ; Steffi Friedrichs ; Sam R. Bailey ; Hee-Gweon Woo ; Manfred Rü ; hle ; John L. Hutchison ; and Malcolm L. H. Green
- 刊名：Journal of the American Chemical Society
- 出版年：2002
- 出版时间：March 13, 2002
- 年：2002
- 卷：124
- 期：10
- 页码：2116 - 2117
- 全文大小：181K
- 年卷期：v.124,no.10(March 13, 2002)
- ISSN：1520-5126
文摘
High-resolution transmission electron microscopy and spatially resolved electron loss spectroscopy have revealed that a eutectic mixture of AgCl and AgI crystallizes within single walled carbon nanotubes (SWNTs) as metastable AgCl1-xIx 1D solid solution crystals. The incorporated halide crystals form wurzite "tunnel" structures with locally varying Cl:I ratios and reduced Ag coordination.