In Situ Generation of Functionality in a Reactive Haloalkane-Based Ligand for the Design of New Porous Coordination Polymers

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• 作者：Prakash Kanoo ; Ryotaro Matsuda ; Hiroshi Sato ; Liangchun Li ; Hyung Joon Jeon ; Susumu Kitagawa
• 刊名：Inorganic Chemistry
• 出版年：2013
• 出版时间：October 7, 2013
• 年：2013
• 卷：52
• 期：19
• 页码：10735-10737
• 全文大小：231K
• 年卷期：v.52,no.19(October 7, 2013)
• ISSN：1520-510X

文摘

Herein, we report new porous coordination polymers (PCPs) via a facile synthetic approach called 鈥渋n situ generation of functionality in the ligand鈥? Upon a synthetic process of PCPs, a neutral (鈭扖H₂OH) or a cationic functionality (鈭扖H₂-[4,4鈥?bipyridine]⁺) was generated on a isophthalate ligand from a reactive haloalkane (鈭扖H₂Br) moiety, affording two new PCPs. The PCPs have two-dimensional layered structures with large potential solvent-accessible voids for CO₂ adsorption.