Reactivity of Ortho-Palladated Phenol Derivatives with Unsaturated Molecules. Carbodiimide Insertion into a C-Pd Bond and/or O-H Phenol Addition to a Carbodiimide

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• 作者：José ; Vicente ; José ; Antonio Abad ; Mar&iacute ; a-José ; Ló ; pez-Sá ; ez ; and Peter G. Jones
• 刊名：Organometallics
• 出版年：2006
• 出版时间：April 10, 2006
• 年：2006
• 卷：25
• 期：8
• 页码：1851 - 1853
• 全文大小：121K
• 年卷期：v.25,no.8(April 10, 2006)
• ISSN：1520-6041

文摘

The first examples of the insertion of carbodiimidesinto a late-transition-metal-carbon bond and the unprecedentedintramolecular addition of a phenol to a carbodiimide haveallowed the synthesis of O,N and O,C six-membered palladacycles.