Incorporation of 2,6-Di(4,4'-dipyridyl)-9-thiabicyclo[3.3.1]nonane into Discrete 2D Supramolecules via Coordination-Driven Self-Assembly

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• 作者：Hai-Bo Yang ; Neeladri Das ; Feihe Huang ; Adam M. Hawkridge ; David D. D&iacute ; az ; Atta M. Arif ; M. G. Finn ; David C. Muddiman ; Peter J. Stang
• 刊名：Journal of Organic Chemistry
• 出版年：2006
• 出版时间：August 18, 2006
• 年：2006
• 卷：71
• 期：17
• 页码：6644 - 6647
• 全文大小：108K
• 年卷期：v.71,no.17(August 18, 2006)
• ISSN：1520-6904

文摘

D=jo0608117n00001>The synthesis and characterization of three new supramolecular complexes 6-8 (a rhomboid and two hexagons) viacoordination-driven self-assembly are reported in excellentyields (>90%). These assemblies have 2,6-di(4,4'-dipyridyl)-9-thiabicyclo[3.3.1]nonane 2 as the bridging tecton. Allassemblies were characterized by multinuclear NMR (¹H and³¹P), mass spectrometry (ESI-MS and ESI-FT-ICR), andelemental analysis. The X-ray structure of the 120deg.gif"> tecton 2is also discussed.