Gold-Catalyzed Intermolecular Hetero-Dehydro-Diels-Alder Cycloaddition of Captodative Dienynes with Nitriles: A New Reaction and Regioselective Direct Access to Pyridines

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• 作者：José ; Barluenga ; Manuel Á ; ngel Ferná ; ndez-Rodr&iacute ; guez ; Patricia Garc&iacute ; a-Garc&iacute ; a ; Enrique Aguilar
• 刊名：Journal of the American Chemical Society
• 出版年：2008
• 出版时间：March 5, 2008
• 年：2008
• 卷：130
• 期：9
• 页码：2764 - 2765
• 全文大小：53K
• 年卷期：v.130,no.9(March 5, 2008)
• ISSN：1520-5126

文摘

For the first time, nitriles are used as 2 electron component in a gold-catalyzed intermolecular Hetero-Dehydro-Diels-Alder cycloaddition with captodative enynes leading to the regioselective formation of pyridines.