Antiferromagnetic Interaction Achieved by a 3-D Supramolecular CuII Complex with Pyrazino-Fused TTF as the Ligand, [CuCl2(BP-TTF)]

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• 作者：Shun Ichikawa ; Shinya Kimura ; Hatsumi Mori ; Gosuke Yoshida ; Hiroyuki Tajima
• 刊名：Inorganic Chemistry
• 出版年：2006
• 出版时间：September 18, 2006
• 年：2006
• 卷：45
• 期：19
• 页码：7575 - 7577
• 全文大小：96K
• 年卷期：v.45,no.19(September 18, 2006)
• ISSN：1520-510X

文摘

The diffusion reaction of TBA₂Cu^IICl₄ (TBA = tetrabutylammonium)and a N-containing organic donor, BP-TTF [=bis(pyrazino)tetrathiafulvalene], yielded a 3-D supramolecular Cu complex,[CuCl₂(BP-TTF)] (1). The magnetic measurement of 1 exhibits anantiferromagnetic interaction by fitting a Bonner-Fisher model from2 to 300 K with S = ¹/₂ and J = -3.5 K between Cu mediatedby self-assembling donor columns.