Prospects for Obtaining High Quality Fuels from the Hydrocracking of a Hydrotreated Scrap Tires Pyrolysis Oil

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• 作者：Idoia Hita ; Elena Rodr铆guez ; Martin Olazar ; Javier Bilbao ; Jos茅 Mar铆a Arandes ; Pedro Casta帽o
• 刊名：Energy & Fuels
• 出版年：2015
• 出版时间：August 20, 2015
• 年：2015
• 卷：29
• 期：8
• 页码：5458-5466
• 全文大小：516K
• ISSN：1520-5029

文摘

The hydrocracking of hydrotreated scrap tires pyrolysis oil (HT-STPO) has been studied aiming at high-quality refinery blends for alternative automotive fuels. The hydrocracking runs have been carried out with a PtPd/SiO₂-Al₂O₃ catalyst in a fixed-bed reactor at 440鈥?00 掳C, 65 bar and space time of 0.16 h. The catalyst has been characterized by inductively coupled plasma optical emission spectroscopy, N₂ adsorption鈥揹esorption isotherms, and tert-butylamine adsorption鈥揹esorption (TPD), while coke has been studied both quantitatively and qualitatively by thermogravimetric-temperature-programmed oxidation (TG-TPO), Fourier transform infrared-TPO, and Raman spectroscopy. During the first two hours of reaction and at temperatures above 480 掳C, we have been able to (1) reach ultra low sulfur levels lower than 15 ppm; (2) remove almost completely the less interesting fraction鈥攂oiling points higher than 350 掳C, named as the gasoil fraction鈥攚ith remaining amounts lower than 1 wt %; (3) obtain a paraffinic and isoparaffinic content higher than 70 wt %. Catalyst deactivation is due to coke deposition having both an aromatic and aliphatic nature, while the aromaticity increases with process temperature. It has been proven that the temperature conditions can be tuned to reach a state in which coke is generated at the same rate that it is being hydrocracked.