Conjugated Microporous Polymers Incorporating BODIPY Moieties as Light-Emitting Materials and Recyclable Visible-Light Photocatalysts

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• 作者：Marta Liras ; Marta Iglesias ; Félix Sánchez
• 刊名：Macromolecules
• 出版年：2016
• 出版时间：March 8, 2016
• 年：2016
• 卷：49
• 期：5
• 页码：1666-1673
• 全文大小：515K
• ISSN：1520-5835

文摘

Here we report the design and synthesis of a new conjugated microporous polymer based on a BODIPY dye (CMPBDP) which has shown excellent luminescence properties and an efficient heterogeneous photocatalytic activity. CMPBDP shows high thermal stability and high surface area with microporous size and efficiently catalyzes the selective oxidation of thioanisole into the corresponding sulfoxide via singlet oxygen under visible light (up to 500 nm). The photocatalytic rate of the heterogeneous materials is 4-fold faster that the corresponding soluble (used as reference) under the same reaction conditions and can be reused several times.