Electroreduction of N2 to Ammonia at Ambient Conditions on Mononitrides of Zr, Nb, Cr, and V: A DFT Guide for Experiments
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- 作者：Younes Abghoui ; Anna L. Garden ; Jakob G. Howalt ; Tejs Vegge ; Egill Skúlason
- 刊名：ACS Catalysis
- 出版年：2016
- 出版时间：February 5, 2016
- 年：2016
- 卷：6
- 期：2
- 页码：635-646
- 全文大小：685K
- ISSN：2155-5435
文摘
A rapid and facile reduction of nitrogen to achieve sustainable and energy-efficient production of ammonia is critical to its use as a hydrogen storage medium, chemical feedstock, and especially for manufacturing inorganic fertilizers. For a decentralization of catalytic ammonia production, small-scale N2 reduction devices are required that are equipped with the most stable, selective, and active catalysts that operate at low temperature and ambient pressure. Here, we report the development of new and cost-efficient catalysts, transition metal nitrides, which enable electrochemical reduction of molecular nitrogen to ammonia in aqueous media at ambient conditions with only a low applied bias. The most promising catalysts are VN, ZrN, NbN, and CrN, which are identified among a range of transition metal nitride surfaces through a comprehensive density functional theory based analysis. All four nitrides are found to be more active toward nitrogen reduction than toward the competing hydrogen evolution reaction, in contrast to pure metal catalysts, which largely evolve hydrogen. Furthermore, their stability against poisoning and possible decomposition under operating conditions is also studied. Particular single-crystal surfaces are needed for ZrN, NbN, and CrN because polycrystalline surfaces may result in decomposition of the whole catalyst. Polycrystalline surfaces of VN may, however, be used since the rocksalt (100) facet is predicted to produce ammonia via a Mars–van Krevelen mechanism with only a ?0.5 V overpotential, thereby avoiding decomposition. We suggest that this is a promising step toward the development of a method for synthesizing ammonia cheaply, to prepare high-value-added nitrogenous compounds directly from air, water, and electricity at ambient conditions. An additional benefit to the present analysis is that the method used in this work may be applicable to other aqueous phase catalytic reactions, where a Mars–van Krevelen mechanism is operative and product selectivity and activity are key catalytic criteria.