In(SAr)3 As a Building Block for 3D and Helical Coordination Polymers
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- 作者：Johanna Heine ; Ma艂gorzata Ho艂y艅ska ; Marco Reuter ; Benedikt Haas ; Sangam Chatterjee ; Martin Koch ; Katharina I. Gries ; Kerstin Volz ; Stefanie Dehnen
- 刊名：Crystal Growth & Design
- 出版年：2013
- 出版时间：March 6, 2013
- 年：2013
- 卷：13
- 期：3
- 页码：1252-1259
- 全文大小：453K
- 年卷期：v.13,no.3(March 6, 2013)
- ISSN：1528-7505
文摘
In(SAr)3 (Ar = phenyl or p-tolyl) was employed as a building block to construct coordination polymers [(In(SPh)3)3(tpt)2] (1, tpt = 2,4,6-tris(4-pyridyl)triazine), [In(SPh)2(2-PCIH)] (2, 2-HPCIH = 2-pyridinecarbaldehyde isonicotinoylhydrazone), and [(In(S(p-tol))2)(2-PCIH)]路2MeOH (3). Compound 1 is an intricate 3D coordination polymer displaying superstructure effects on its X-ray diffraction pattern, which have been additionally studied by transmission electron microscopy (TEM). Compounds 2 and 3 are helical coordination polymers. Whereas 3 comprises helices of both rotational handednesses in its crystal structure, 2 possesses only one enantiomeric form and thus exhibits a noncentrosymmetric structure that displays an SHG effect.