Reaction of Corey Ylide with 伪,尾-Unsaturated Ketones: Tuning of Chemoselectivity toward Dihydrofuran Synthesis
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- 作者：Alexey O. Chagarovsky ; Ekaterina M. Budynina ; Olga A. Ivanova ; Elena V. Villemson ; Victor B. Rybakov ; Igor V. Trushkov ; Mikhail Ya. Melnikov
- 刊名：Organic Letters
- 出版年：2014
- 出版时间：June 6, 2014
- 年：2014
- 卷：16
- 期：11
- 页码：2830-2833
- 全文大小：279K
- 年卷期：v.16,no.11(June 6, 2014)
- ISSN：1523-7052
文摘
A straightforward, efficient, and reliable approach to synthetically valuable 2,3-dihydrofurans via a reaction between Corey ylide and 伪,尾-unsaturated ketones has been developed. The use of simple and widely spread starting materials as well as mild reaction conditions and scalability provide a broad scope of 2,3-dihydrofurans.