Radical Mechanism in the Elimination of 2-Arylsulfinyl Esters

详细信息    查看全文

• 作者：Antonio Latorre ; Irakusne L贸pez ; Victoria Ram铆rez ; Santiago Rodr铆guez ; Javier Izquierdo ; Florenci V. Gonz谩lez ; Cristian Vicent
• 刊名：The Journal of Organic Chemistry
• 出版年：2012
• 出版时间：June 1, 2012
• 年：2012
• 卷：77
• 期：11
• 页码：5191-5197
• 全文大小：318K
• 年卷期：v.77,no.11(June 1, 2012)
• ISSN：1520-6904

文摘

The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray ionization tandem mass spectrometry and experimental work. Rearranged sulfoxides are obtained as byproduct during the elimination reaction.