Insertion of a N-Heterocyclic Carbene (NHC) into a Platinum-Olefin Bond
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文摘
The insertion of a N-heterocyclic carbene (NHC) intoa coordinated olefin moiety is observed for a Pt-based system.Important intermediates along the reaction pathway have beenisolated and fully characterized. Computational work supportsa proposed mechanistic pathway involving external attack atthe olefin by a NHC ligand rather than an intramolecularmigratory insertion route.

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