Synthesis and Structure of Base-Stabilized Germanium(II) Diazide IPrGe(N3)2

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• 作者：Benjamin Lyhs ; Dieter Bl盲ser ; Christoph W枚lper ; Stephan Schulz ; Rebekka Haack ; Georg Jansen
• 刊名：Inorganic Chemistry
• 出版年：2013
• 出版时间：June 17, 2013
• 年：2013
• 卷：52
• 期：12
• 页码：7236-7241
• 全文大小：277K
• 年卷期：v.52,no.12(June 17, 2013)
• ISSN：1520-510X

文摘

Coordination of a strong 蟽-base has been shown to be an effective method for the stabilization of low valent main group element complexes. This general method was now used for the synthesis of the divalent germanium diazide. IPrGe(N₃)₂1 represents the first neutral homoleptic germanium diazide that could be structurally characterized.