Oxygen-Doped Nanodiamonds: Synthesis and Functionalizations
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- 作者：Andrey A. Fokin ; Tatyana S. Zhuk ; Alexander E. Pashenko ; Pavlo O. Dral ; Pavel A. Gunchenko ; Jeremy E. P. Dahl ; Robert M. K. Carlson ; Tatyana V. Koso ; Michael Serafin ; Peter R. Schreiner
- 刊名：Organic Letters
- 出版年：2009
- 出版时间：July 16, 2009
- 年：2009
- 卷：11
- 期：14
- 页码：3068-3071
- 全文大小：193K
- 年卷期：v.11,no.14(July 16, 2009)
- ISSN：1523-7052
文摘
Oxadiamondoids representing a new class of carbon nanoparticles were prepared from the respective diamondoid ketones via an effective two-step procedure involving addition of methyl magnesium iodide and oxidation with trifluoroperacetic acid in trifluoroacetic acid. The reactivities of the oxacages are determined by the position of the dopant and are in good agreement with computational predictions.